Product ID:ID 775-7325, 81-67-1 USDA BLUE TMP
MSDS Date:05/03/1990
FSC:8010
NIIN:01-274-2573
MSDS Number: BHXJJ

SOUTHERN COATINGS

SUMTER, SC 29150
US

Emergency Phone: 803-775-6351

Info Phone: 803-775-6351

Preparer: SOUTHERN COATINGS

Cage: 6M840

SOUTHERN COATINGS

160 SUMTER, SC 29150 US

Telephone: 803-775-6351

Cage: 6M840

TITANIUM DIOXIDE

CAS: 13463-67-7

RTECS: XR2275000

OSHA PEL 15 MG/M3 TDUST

ACGIH TLV: 10 MG/M3 TDUST; 9293

MINERAL SPIRITS (VAPOR PRESSURE 2 MMHG @ 20 DEG C)

CAS: 64742-88-7

OSHA PEL 100 PPM/525 MG/CU.M

ACGIH TLV: 100 PPM/525 MG/CU.M.

VOC. 4.86 LB/GAL LESS WATER & NEGLIGIBLY PHOTOCHEMICALLY

RTECS: 9999999VO

VOC. 19.21 LB/GAL SOLIDS 2305 G/L SOLIDS CALCULATED

RTECS: 9999999VO

Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:NO IARC:NO OSHA:NO
Health Hazards Acute and Chronic:REPORTS HAVE ASSOCIATED PROLONGED &
REPEATED OCCUPATIONAL OVEREXPOSURE TO SOLVENTS WITH PERMANENT BRAIN
& NERVOUS SYSTEM DAMAGE. INTENTIONAL MISUSE BY DELIBERATELY
CONCENTRATING & INHALING THE CONTENT S MAY BE HARMFUL OR FATAL.
ACUTE CENTRAL NERVOUS SYSTEM DEPRESSION, CHARCTERIZED:HEADACHE,
DIZZINESS NAUSEA & CONFUSION.
Explanation of Carcinogenicity:AT THE TLV TIO2 MANUFACTURER CONCLUDES
THAT THERE IS NO SIGNIFICANT HAZARD FOR MAN. SEE FILE FOR
ADDITIONAL INFORMATION.
Effects of Overexposure:SWALLOW: CAN CAUSE GASTROINTESTINAL IRRITATION,
NAUSEA, VOMITING. ASPIRATION OF MATERIAL INTO LUNGS MAY CAUSE
CHEMICAL PNEUMONITIS WHICH CAN BE FATAL. INHALATION: MAY CAUSE NOSE
OR THROAT IRRITATION, HEADACHE, DIZZINESS, NAUSEA & CONFUSION.
EYES: IRRITATION. SKIN: MAY CAUSE DEFATTING & IRRITATION OF THE
SKIN.

First Aid:SWALLOW: DO NOT INDUCE VOMIT. CALL POISON CONTROL
CENTER/EMERG ROOM/PHYSICIAN IMMED. INHALED: REMOVE TO FRESH AIR
IMMED. IF BREATH STOPPED, GIVE CPR. KEEP WARM & QUIET. GET MED ATTN
IMMED. EYES: FLUSH WITH LARGE AMTS OF WATER, LIFTING LIDSFOR AT
LEAST 15 MINS. GET MED ATTN. SKIN: REMOVE CONTAMINATED CLOTHES.
WASH AFFECTED AREA WITH SOAP AND WATER. OBTAIN MEDICAL ATTENTION IF
IRRITATION PERSISTS.

Flash Point:>102 F/>39 C
Extinguishing Media:NFPA CLASS B FIRE EXTINGUISHERS FOR FLAMMABLE
LIQUID FIRES. POLYMER FOAM PREFERRED FOR LARGE FIRES.
Fire Fighting Procedures:WEAR SCBA.WATER MAY BE INEFFECT: USE TO COOL
EXPOSED CONTAINER.PREVENT PRESSURE BUILD-UP.AUTO-IGNITE/EXPLOSION
FROM EXTREME HEAT.IF WATER USED-FOG NOZZLE PREFER
Unusual Fire/Explosion Hazard:OVEREXPOSURE TO DECOMP PRODUCT MAY BE
HEALTH HAZARD. KEEP CONTAINERS TIGHTLY CLOSED. ISOLATE FROM HEAT,
ELECTRIC EQUIP, SPARKS & FLAME. CLOSED CONTAINER MAY *

Spill Release Procedures:KEEP SPECTATORS AWAY. ELIM ALL IGNITION
SOURCES(FLAMES,HOT SURFACES,SOURCES OF ELECTRIC, STATIC OR FRICTION
SPARKS)DIKE & CONTAIN SPILL W/INERT MATERIAL(E.G. SAND,EARTH).
TRANS LIQ TO COVERED METAL CO NTAINER FOR
RECOVERY/DISPOSAL/REMOVAL. PREVENT **
Neutralizing Agent:N/K. **CONTAMINATION OF SEWERS, STREAMS, &
GROUNDWATER W/MATERIAL/USED ABSORBENT

Handling and Storage Precautions:DO NOT STORE ABOVE 95 DEG F. STORE
LARGE AMOUNTS IN COMPLIANCE W/OSHA 29CFR1910.106.
Other Precautions:DO NOT TAKE INTERNALLY. CLOSE CONTAINER AFTER EACH
USE. EMPTY CONTAINERS MUST NOT BE WASHED AND RE-USED FOR ANY
PURPOSE. CONTAINERS SHOULD BE GROUNDED AND BONDED TO THE RECEIVING
CONTAINER.

Respiratory Protection:GENERAL EXPOSURE TO ORGAN CHEM MAY NOT REQUIRE
USE OF RSPRTR IN WELL VENTED AREA. RESTRICT VENT:NIOSH CHEM
CARTRIDGE MAY BE NEEDED. SPRAYING:MECH PREFILTER MAY BE REQUIRED.
CONFINED AREA:NIOSH/MSHA AI R SUPPLIED RSPRTR.SEE FILE FOR MORE
INFO
Ventilation:GENERAL DILUTION & LOCAL EXHAUST VENT IN SUFFICIENT
VOL/PATTERN TO MAINTAIN CONCENTRATIONS OF HAZARD BELOW LOWEST
LIMITS
Protective Gloves:SOLVENT IMPERMEABLE GLOVES
Eye Protection:WEAR SAFETY SPECTACLES.
Other Protective Equipment:NOT LIKELY TO BE NEEDED.
Work Hygienic Practices:AVOID BREATHING VAPORS OR MIST.
Supplemental Safety and Health
NOTE: ANY TREATMENT THAT MIGHT BE REQUIRED FOR OVEREXPOSURE SHOULD BE
DIRECTED AT THE CONTROL OF SYMPTOMS & THE CLINICAL CONDITIONS.
PRODUCT, IF DISCARDED DIRECTLY, WOULD BE CLASSIFIED HAZARDOUS WASTE
BASED ON ITS IGNITABILITY CHARACTERISTIC, I.E. HAS A FLASH POINT
OF 140 F. OR LESS. PROPER RCRA CLASSIFICATION DOO1.

Boiling Pt:B.P. Text:>280F,>138C
Vapor Density:> THAN AIR
Evaporation Rate & Reference:SLOWER THAN ETHER
Percent Volatiles by Volume:74

Stability Indicator/Materials to Avoid:YES
STRONG ACIDS OR ALKALINE MATERIALS.
Stability Condition to Avoid:AVOID EXCESS HEAT & SOURCES OF IGNITE. *
EXPLODE FROM EXTREME HEAT.
Hazardous Decomposition Products:BURNING, INCLUDING WHEN HEATED BY
WELDING OR CUTTING, WILL PRODUCE SMOKE, CARBON MONOXIDE AND CARBON
DIOXIDE.
Conditions to Avoid Polymerization:KEEP AWAY FROM HEAT, SPARKS AND
FLAME.

Waste Disposal Methods:DISPOSE IN ACCORDANCE WITH FEDERAL, STATE AND
LOCAL LAWS.

Disclaimer (provided with this information by the compiling agencies):
This information is formulated for use by elements of the Department
of Defense. The United States of America in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.